Palladium on Carbon Catalysts

Palladium on Carbon Catalysts

Palladium on Activated Charcoal is also known as Palladium on Carbon (Pd on C) is a mild hydrogenation catalyst. It is generally a catalyst of choice when the functional group to be hydrogenated is a part of a molecule which has also got some other functional group capable of getting hydrogenated. It is also a catalyst of choice for getting a specific type of isomer. It is, therefore, a catalyst for selective hydrogenation. Further, it can also be safely used where the reaction conditions are acidic, viz. where acetic acid is a solvent or dilute sulphuric acid or di-hydro chlorine is additive.

Vineeth Precious Catalysts Pvt. Ltd., Vasai, makes multiple standard grades of Palladium on Carbon. Different grades are made for attaining better yield and efficiency with different type of reactions. These grades can meet requirements for all types of hydrogenation reactions where palladium on carbon is recommended catalyst.

In each of these grades, palladium loading can be made as per customer's requirements. For reasons of economy, it is quite customary to use the same catalyst for more than one cycle of hydrogenation before it is sent to the manufacturer for recovery of palladium metal for an eventual reformulation of fresh catalyst. However, if the nature of the reactants and the end products are such that the catalyst gets deactivated or poisoned after one cycle only, it is advisable to opt for lower palladium loading viz. 1% or 2% instead of standard 5% or 10%.

Palladium on Carbon Catalyst, especially when Palladium loading is high, is usually supplied in Wet Form, i.e with 50% water because of pyrophoric nature of dry powder in the environment of Hydrogen. Catalyst powder in dry form is however used when presence of water is totally undesirable.

A reference table annexed herewith shows which grade is more suitable for a particular type of reaction. The recommendation given in the table should however be taken as a suggestive one and not an ultimate one.

Certificate of Analysis (COA) is made available to all the customers irrespective of quantum of supply. Material safety information, technical specification are supplied against specific request.

Packing :-

Standard packing is 1 kg, 2 kg and 5 kg in wet or dry form as per customer's requirement.

Shelf Life :-

The assured shelf life of the product is one year from the date of manufacture with retest period of six months.

Note :-
  1. Different Grade Nos of Catalyst are on account of different grades of activated charcoal used and different techniques adopted at the time of making of the catalyst.
  2. All the above catalysts can also be supplied in wet form with 50% water
GRADES OF PALLADIUM ON CARBON CATALYSTS & THEIR TYPICAL APPLICATIONS
Catalyst Grade

Palladium Content

Typical Application
300 Z

2.0%
2.5%
3.0%
5.0%

Carbonyl Reduction
Dehalogenation
C-N and C-O cleavage
Aromatic and Aliphatic Nitro/
Nitroso group Hydrogenation

300 V

2.0%
2.5%
3.0%
5.0%

C-N and C-O cleavage
Reduction of Olefins to Paraffin
Debenzylation

390 Z

2.0%
2.5%
3.0%
5.0%
10.0%

Rosenmund Reduction
Rosin disproportionation
Dehalogenation
Reductive Alkylation/Amination
Aromatic Nitro group Hydrogenation
Hydrogenation of
Acetylene and Olefins to Paraffin
Hydrogenation of Aromatic
Aldehyde and Ketones to Alcohol

390 V

2.0%
2.5%
3.0%
5.0%
10.0%

Debenzylation

Dehydrogenation
153 V

20% Pd (OH)2 on Carbon

Debenzylation

TOP